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| Education |
| Postdoctoral University of
Rochester, Rochester, NY |
| Ph.D. 1997 Dalhousie University,
Halifax, Nova Scotia, Canada |
| M.Sc. 1991 Leiden
University, Leiden, The Netherlands |
| B.Sc. 1989 Van Leeuwenhoek
Institute, Delft, The
Netherlands | |
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Dr. de Lijser's research
interests are in the area of environmental organic photochemistry.
Currently we are studying the structure and reactivity of naturally
occurring compounds (drugs, pesticides, dyes) containing a
carbon-nitrogen double bond (oximes, oxime ethers, hydrazones,
azines) upon photochemical excitation and one-electron oxidation.
Specific interests include the generation of reactive species
(radicals, radical ions) via surface-catalyzed photochemical
reactions (pesticides; environmental) and enzyme-catalyzed
oxidations (drugs; toxicology) of model compounds.
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| Recent Publications |
- H.J.P de Lijser, N.A. Rangel, M. Tetalman and C.K. Tsai, Mechanisitic Aspects of the Formation of Aldehydes and Nitriles in Photosensitized Reactions of Aldoxime Ethers, J. Org. Chem., 72, 4126-4134 (2007).
- H.J.P de Lijser, S. Hsu, B.V. Marquez, A. Park, N. Sanguantrakun, and J. R. Sawyer, Effects of Structure in Benzaldehyde Oximes on th Formation of Aldehydes and Nitriles Under Photoinduced Electron Transfer Conditions, J. Org. Chem., 71, 7785-7792 (2006).
- A. Park, N.M. Kosareff, J.S. Kim, and H.J.P. de Lijser, Quinone-Sensitized Steady-Stat Photolysis of Acetophenone Oximes Under Aerobic Conditions: Kinetics and Product Studies, Photochem. Photobiol., 82, 110-118 (2006).
- H.J.P. de Lijser and N. A. Rangel, Photochemical Acetalization of Carbonyl Compounds in Protic Media Using an in Situ Generated Photocatalyst, J. Org. Chem., 69. 8315-8322 (2004).
- H.J.P de Lijser and C.K. Tsai, Photosensitized Reactions of Oxime Ethers. A Steady-State and Laser Flash Photolysis Study, J. Org. Chem., 69. 3057-3067 (2004).
- H.J.P. de Lijser, C.E. Dedeian, J.R. Sawyer, S.R. Herron, and K.A. Kantardjieff, Preparation and Structure of an Unexpected Dehydrogenation Product from 2,6-Diphenylcyclohexanone Oxime, J. Chem. Cryst., 34, 103-110 (2004).
- H.J.P. de Lijser, J.S. Kim, S.M. McGrorty, and E.M. Ulloa, Substituent Effects in Oxime Radical Cation. 1. Photosensitized Reactions of Acetophenone Oximes, Can. J. Chem., 81, 575-585 (2003).
- H.J.P. de Lijser, F.H. Fardoun, J.R. Sawyer, and M. Quant, Photosensitized Regeneration of Carbonyl Compounds From Oximes, Org. Lett., 4, 2325-2328 (2002).
- H.J.P. de Lijser, D.W. Snelgrove, and J.P. Dinnocenzo, Nucleophilic Substitutions on Silane Cation Radicals: Stepwise or Concerted?, J. Am. Chem. Soc., 123, 9698-9699 (2001).
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